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hhchang_

A. Hsiu Hua Chang

Professor,  Physical Chemistry 
　

 

 

 

 

 

   Phone

Office：(03)-890-3595

Lab   ：(03)-890-3596

   Office

C116  Science building 2

   Laboratory

C114  Science building 2

   e-mail

hhchang@gms.ndhu.edu.tw

 

  Personal Website

 

 
  Education

 

1991: Ph. D., Department of Chemistry, Ohio State University, U. S. A.
1985: B.A., Department of Chemistry, National Sun Yat-Sen University
 

  Experience

 

Postdoctor, Ohio state University

Postdoctor, Johns Hopkins University, U.S. A .

Postdoctor, Vienna University

Postdoctor, Academia Sinica, Taiwan

  Research Interests

　

1. Theoretical Chemistry
 
2. Chemical Dynamics
 
3. Electronic Structure of Organometal and Molecular Clusters
 
4. Non-adiabatic Process
 

  Selected Publications

 

  1. “Formation of the Elusive Silylenemethyl Radical (HCSiH2; X2B2) via the Unimolecular Decomposition of Triplet Silaethylene (H2CSiH2; a3A")” C. He, A. M. Thomas, B. B. Dangi, T. Yang, R. I. Kaiser*, H. C. Lee, B. J. Sun, and A. H. H. Chang* J. Phys. Chem. A, 126, 3347 (2022/Jun) (IF=2.944, ▼:0)
  2. “Gas Phase Preparation of the Elusive Monobridged Ge(µ -H)GeH Molecule via Non-Adiabatic Reaction Dynamics” Z. H. Yang,+ B. J. Sun,+ C. He, S. Fatimah, A. H. H. Chang,* R. I. Kaiser* Chem. Eur. J., e202103999 (2022/Jan) (IF=5.020, ▼:0).
  3. “A Spectroscopic Investigation on the Oxidation of exo-Tetrahydrodicyclopentadiene (JP-10; C10H16) Doped with Titanium-Aluminum-Boron Reactive Metal Nanopowder” S. J. Brotton, S. D. Perera, A. Misra, N. F. Kleimeier, A. M. Turner, R. I. Kaiser,* M. Palenik,* M. T. Finn, A. Epshteyn,* B. J. Sun, L. J. Zhang, A. H. H. Chang,* J. Phys. Chem. A, J. Phys. Chem. A, 126, 125 (2022/Jan) (IF=2.944, ▼:1).
  4. “Facile synthesis of indoline-fused 2,5-diketopiperazine scaffolds via Ugi-4CR in the basic mediated tandem consecutive cyclization” C. Y. Wu, S. P. Murugan, Y. W. Wang, H. W. Pan, B. J. Sun, Y. T. Lin, S. Fatimah, A. H. H. Chang,* C. Chen,* and G. H. Lee, Adv. Synth. Catal., 363, 4960 (2021/Nov) (IF=5.980, ▼:3).
  5. “Identification of Elusive Keto and Enol Intermediates in the Photolysis of 1,3,5-Trinitro-1,3,5- Triazinane (RDX)” S. K. Singh., V. Vuppuluri, B. J. Sun, B. Y. Chang, A. K. Eckhardt, S. F. Son, A. H. H. Chang,* Ralf I. Kaiser,* J. Phys. Chem. Lett., 12, 6062 (2021/Jun) (IF=6.888, ▼:1).
  6. “Formation of Phosphine Imide (HN=PH3) and its Phosphinous Amide (H2N-PH2) Isomer” C. Zhu, A. Bergantini, S. K. Singh, R. I. Kaiser* A. K. Eckhardt, * P. R. Schreiner, Y. S. Huang, B. J. Sun, A. H. H. Chang,* Chem. Comm., 57, 4958 (2021/Apr) (IF=6.065, ▼:1)
  7. “A Combined Experimental and Computational Study on the Reaction Dynamics of the D1-Silylidyne (SiD) - Silane (SiH4) System” Z. H. Yang,† B. J. Sun,† C. He, S. Goettl, Y. T. Lin, A. H. H. Chang,* R. I. Kaiser,* J. Phys. Chem. A, 125, 2472 (2021/Apr) (IF=2.944, ▼:3). †co-first author
  8. “Solvent-Induced Luminescence and Structural Transformation of a Dinuclear Gold(I) (Aza-18-crown-6)dithiocarbamate Compound” B. C. Tzeng,* C. Y. Lin, J. W. Hung, S. Y. Chen, A. H. H. Chang,* and G. H. Lee, Inorg. Chem. 60, 2694 (2021/Jan) (IF= 5.436, ▼:0)
  9. “Gas phase identification of the elusive oxaziridine (cyclo-H2CONH) - an optically active molecule” S. K. Singh, J. L. Jeunesse, C. Zhu, N. F. Kleimeier, K. H. Chen, B. J. Sun, A. H. H. Chang,* R. I. Kaiser,* Chem. Comm., 56, 15643 (2020/Dec) (IF=6.065, ▼:1).
  10. “Gas Phase Synthesis of the Elusive Trisilacyclopropyl Radical (Si3H5) via Unimolecular Decomposition of Chemically Activated Doublet Trisilapropyl Radicals (Si3H7)” S. Doddipatla, Z. H. Yang, A. M. Thomas, Y. L. Chen, B. J. Sun, A. H. H. Chang,* Alexander M. Mebel,* and R. I. Kaiser,* J. Phys. Chem. Lett., 11, 7874 (2020/Aug) (IF=6.888, ▼:0).
  11. “Gas Phase Identification of the Elusive N-Hydroxyoxaziridine (c-H2CON(OH)) – A Chiral Molecule” S. K. Singh, T. Y. Tsai, B. J. Sun, A. H. H. Chang,* A. M. Mebel, R. I. Kaiser,* J. Phys. Chem. Lett., 11, 5383 (2020/Jun) (IF=6.888, ▼:6).
  12. “The Elusive Ketene (H2CCO) Channel in the Infrared Multiphoton Dissociation of Solid 1,3,5-Trinitro-1,3,5-Triazinane (RDX)” Santosh K. Singh, Jesse La Jeunesse, Vasant Vuppuluri, Steven F. Son, Y. L. Chen, B. J. Sun, A. H.H, Chang,* R. I. Kaiser,* Chem. Phys. Chem., 21, 837 (2020/May) (IF=3.520, ▼:4)
  13. “Synthesis of Polycyclic Aromatic Hydrocarbons by Phenyl Addition– Dehydrocyclization: The Third Way” L. Zhao, M. Prendergast, R. I. Kaiser*, Bo Xu, U. Ablikim, M. Ahmed*, B. J. Sun, Y. L. Chen, A. H. H. Chang,* R. K Mohamed, F. R. Fischer,* Angew. Chem. Int. Ed. , 58, 17442 (2019/Nov) (IF=16.823, ▼:20)..
  14. “Origin of alkylphosphonic acids in the interstellar medium” A. M. Turner, M. J. Abplanalp, A. Bergantini, R. Frigge, C. Zhu, B. J. Sun, C. T. Hsiao, A. H. H. Chang,* C. Meinert*, R. I. Kaiser,* Science Advances, 5, eaaw4307 (2019/Aug) (IF=14.957, ▼:7).
  15. “A Crossed Molecular Beams Investigation of the Reactions of Atomic Silicon (Si(3P)) with C4H6 Isomers (1,3-Butadiene, 1,2-Butadiene, and 1-Butyne)” A. M. Thomas, T. Yang, B. B. Dangi, B. J. Sun, T. J. Chou, A. H. H. Chang,* R. I. Kaiser,* Chem. Phys, 520, 70 (2019/Apr) (IF=2.552, ▼:2).
  16. “Directed Gas-Phase Formation of the Germaniumsilylene Butterfly Molecule (Ge(µ−H₂)Si)” A. M. Thomas, T. Yang, B. B. Dangi, G. Tarczay, B. J. Sun, S. Y. Chen, A. H. H. Chang,* R. I. Kaiser* T. L. Nguyen, J. F. Stanton*, A. M. Mebel,* J. Phys. Chem. Lett., 10, 1264 (2019/Mar) (IF=6.888, ▼:6).
  17. “Fluorescence Turn-on Chemosensors Based on Surface-functionalized MoS2 Quantum Dots” T. W. Lin, D. Namasivayam, H. L. Lee, Y. T. Lin, K. C. Lin*, A. H. H. Chang,* Sensors & Actuators: B. Chemical, 281, 659 (2019/Feb) (IF=9.221, ▼:18).
  18. “A Vacuum Ultraviolet Photoionization Study on the Formation of Methanimine (CH2NH) and Ethylenediamine (NH2CH2CH2NH2) in Low Temperature Interstellar Model Ices Exposed to Ionizing Radiation” C. Zhu, R. Frigge, A. M. Turner, M. J. Abplanalp, B. J. Sun, Y. L. Chen, A. H. H. Chang,* R. I. Kaiser,* Phys. Chem. Chem. Phys, 21, 1952 (2019/Jan) (IF=3.945, ▼:5).
  19. “An interstellar synthesis of phosphorus oxoacids” A. M. Turner, A. Bergantini, M. J. Abplanalp, C. Zhu, S. Góbi, B. J. Sun, K. H. Chao, A. H. H. Chang, C. Meinert, R. I. Kaiser,* Nature comm., 9, 3851 (2018/Sep) (IF=17.694, ▼:26).
  20. “Synthesis of the hitherto elusive formylphosphine (HCOPH2) in the interstellar medium - a molecule with an exotic phosphorus peptide bond” R. Frigge, C. Zhu, A. M. Turner, M. J. Abplanalp, B. J. Sun, Y. S. Huang, A. H. H. Chang,* R. I. Kaiser,* Chem. Comm., 54, 10152 (2018/Sep) (IF=6.065, ▼:7).
  21. “A Vacuum Ultraviolet Photoionization Study on the Formation of N-Methyl Formamide (HCONHCH3) in Deep Space – A Potential Interstellar Molecule with a Peptide Bond” R. Frigge, C. Zhu, A. M. Turner, M. J. Abplanalp, A. Bergantini, B. J. Sun, Y. L. Chen, A. H. H. Chang, R. I. Kaiser,* Astrophys. J., 862, 84 (2018/Jul) (IF=5.521, ▼:15).
  22. “Are Nonadiabatic Reaction Dynamics the Key to Novel Organosilicon Molecules? The Silicon (Si(3P))-Dimethylacetylene (C4H6(X1A1g)) System as a Case Study” A. M. Thomas, B. B. Dangi, T. Yang, R. I. Kaiser*, L. Lin, T. J. Chou, A. H. H. Chang,* J. Phys. Chem. Lett., 9, 3340 (2018/Jun) (IF=6.888, ▼:4).
  23. “First Identification of Phosphino Formic Acid (H2PCOOH)” C. Zhu, R. Frigge, A. M. Turner, R. I. Kaiser*, B. J. Sun, S. Y. Chen, A. H.H. Chang,* Chem. Comm., 54, 5716 (2018/Jun) (IF=6.065, ▼:11).
  24. “Probing Cl2 Elimination in 248 nm Photolysis of (COCl)2 Using Cavity Ring-down Absorption Spectroscopy” T. K. Huang, , B. J. Chen, K. C. Lin* , L. L. Hu, B. J. Sun, A. H. H. Chang, J. Phys. Chem. A, 121, 2888 (2017/Dec) (IF=2.944, ▼:6).
  25. “Gas Phase Formation of the Disilavinylidene (H₂SiSi) Transient” T. Yang, B. B. Dangi , R. I. Kaiser,* K. H. Chao, B. J. Sun, A. H. H. Chang,* T. L. Nguyen , J. F. Stanton,* Angew. Chem. Int. Ed., 56, 1264 (2017/Jan) (IF=16.823, ▼:14).
  26. “Gas Phase Synthesis of the Elusive Trisilicontetrahydride Species (Si3H4)” Tao Yang, B. B. Dangi, A. M. Thomas, R. I. Kaiser*, B. J. Sun and A. H. H. Chang,* J. Phys. Chem. Lett., 8, 131 (2017/Jan) (IF=6.888, ▼:0).
  27. “Silicon Quantum Dot-Based Fluorescence Turn-On Metal Ion Sensors in Live Cells” N. Dhenadhayalan, H. L. Lee, K. Yadav, K. C. Lin*, Y. T. Lin, A. H. H. Chang, ACS Appl. Mater. Interfaces, 8, 23953 (2016/Sep) (IF=10.383, ▼:37).
  28. “Formation of the 2,3-Dimethyl-1-Silacycloprop-2-Enylidene Molecule via the Crossed Beam Reaction of the Silylidyne Radical (SiH; X2Π) with Dimethylacetylene” T. Yang, A. M. Thomas, B. B. Dangi, R. I. Kaiser,* M. H. Wu, B. J. Sun, A. H. H. Chang,* J. Phys. Chem. A, 120, 7262 (2016/Sep) (IF=2.944, ▼:4).
  29. “An isomer-specific study of solid nitromethane decomposition pathways – Detection of aci-nitromethane (H2CNO(OH)) and nitrosomethanol (HOCH2NO) intermediates” P. Maksyutenko, M. Förstel, P. Crandall, B. J. Sun, M. H. Wu, A. H. H. Chang,* R. I. Kaiser,* Chem. Phys. Lett., 658, 20 (2016/Aug) (IF=2.719, ▼:14).